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volume thermal expansion equation of state. Several equivalent forms of the relationship find use. Thermal expansion is a physical property of a substance gas liquid or solid to modify its shape length area or volume function of temperature.
A p 1 V d V d T 1 V 1 p 1 p V 1 T displaystyle alpha _pequiv frac 1Vleftfrac dVdTrightfrac 1Vleftfrac 1prightfrac 1pVfrac 1T. A For an ideal gas PV nRT the volume is given by V nRTP so taking the partial derivatives gives kT 1 V V P T 1 V nRT 1 P2 1 P a 1 V V T P 1 V nR P 1 T b For a gas with the equation of state PVm b RT where Vm Vn the molar volume is given by Vm RTP b. A thermal EoS describes a materials reaction to temperature changes.
Find the thermal equation of state.
A For an ideal gas PV nRT the volume is given by V nRTP so taking the partial derivatives gives kT 1 V V P T 1 V nRT 1 P2 1 P a 1 V V T P 1 V nR P 1 T b For a gas with the equation of state PVm b RT where Vm Vn the molar volume is given by Vm RTP b. Superficial expansion is defined as the increase in surface area of the solid on heating. Thermal expansion relates with the expansion and contraction of particles in a substance function of temperature. Full thermodynamic equilibrium values of volume fraction of martensitic phase zeq corresponding to ɛ T values of external state parameters can be determined with the formula z eq kLɛ aT T 0 rp 1 20 ϕ it kLk 2rϕ it obtained from 314 after simple manipulations.